{"product_id":"9783832528478","title":"eta2 Complexes of group 10 with cinnamic acid derivatives; spectroscopic properties, stability, reactivity and application potential as photo-switchable catalysts","description":"\u003cp\u003eHomogeneous catalysts based on transition metals are of high industrial relevance. An important goal for this purpose is the light-induced start of the catalytic reaction. The electronic and steric influence of the olefin ligand upon the spectroscopic properties, stability and reactivity of bistriphenylphosphine-cinnamate and related complexes of group 10 were studied in this thesis. By means of these findings a direct prediction of the reactivity was possible based on the NMR-spectroscopic behaviour. Thus a specific design of photo-switchable complexes was possible, in which the olefin ligand could be cleaved from the metal via a selective light-induced intra-ligand cyclisation. This ring closure was examined with the ligand itself as well as in the complexes, concerning electronic and steric influences.\u003c\/p\u003e","brand":"Logos Verlag","offers":[{"title":"Default Title","offer_id":47041323827440,"sku":"9783832528478","price":103.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0737\/7593\/9824\/files\/9783832528478_p0.jpg?v=1763687477","url":"https:\/\/shop-qa.barnesandnoble.com\/products\/9783832528478","provider":"Barnes \u0026 Noble (DEV)","version":"1.0","type":"link"}