{"product_id":"9783832531973","title":"Macromonomers as a Synthetic Tool for the Construction of Complex Polymer Architectures","description":"\u003cp\u003eFree radical polymerization (FRP) may be adopted to obtain macromolecules with high vinyl end-group fidelity - so-called macromonomers. The occurrence of mid-chain radicals (MCRs) in the FRP of acrylates provides the basis for the facile one-pot - one-step auto-initiated high-temperature polymerization method. The obtained macromonomers with their unsaturated terminus represent versatile synthetic building blocks for constructing polymeric architectures. A macromonomer library was synthesized based on various acrylates and its potential use in further free radical copolymerization and end-group transformation was investigated. The obtained complex polymeric materials were fully characterized via state-of-the-art polymer characterization methods, including electrospray ionization mass spectrometry (ESI-MS) hyphenated with size-exclusion chromatography (SEC\/ESI-MS) and liquid chromatography at critical conditions (LCCC).\u003c\/p\u003e","brand":"Logos Verlag","offers":[{"title":"Default Title","offer_id":47058715476208,"sku":"9783832531973","price":60.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0737\/7593\/9824\/files\/9783832531973_p0.jpg?v=1763687404","url":"https:\/\/shop-qa.barnesandnoble.com\/products\/9783832531973","provider":"Barnes \u0026 Noble (DEV)","version":"1.0","type":"link"}