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Structural Chemistry Program, Griffith University

Introduction to Physical Chemistry

Introduction to Physical Chemistry

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This text provides an introduction to physical chemistry, covering the fundamentals of thermodynamics, kinetics, electrochemistry, transport and catalysis. The content of this text is delivered as one-semester course in the second year at Griffith University (Nathan, Australia) and intended for students in the disciplines of chemistry, biochemistry, engineering and neighbouring disciplines.

Table of Contents
I. Physico-chemical data and resources
1 Periodic table of the elements
2 Resources and databases
3 Units and constants
4 Summary of important formulae and equations

II. Thermodynamics
1 Motivation, revision and introduction of basic concepts
2 Free energy
3 Properties of real systems
4 Exercises

III. Mixtures and phases
1 Why do or don't things mix
2 Liquids
3 Phase equilibria
4 Thermodynamic aspects of phase transitions
5 Mixtures of volatile liquids
6 Exercises

IV. Solutions of electrolytes
1 Fundamental concepts
2 Electrochemical reactions
3 Electrolytes in solution
4 Exercises

V. Molecules in motion
1 Transport processes
2 Molecular motion in liquid solutions
3 Exercises

VI. Kinetics
1 Introduction
2 Reaction rates, rate constants and orders of reaction
3 Rate equations
4 Determination of the rate law
5 Temperature dependence of reaction rates
6 Linking the rate laws with reaction mechanisms
7 Polymerisation kinetics
8 Collision theory
9 Reactions in solution
10 Diffusion control
11 Transition state theory
12 Exercises

VII. Catalysis
1 Homogeneous catalysis
2 Heterogeneous Catalysis
3 Methods to investigate surfaces and surface processes
4 Exercises

VIII. Mathematical appendix
1 Basic algebra and operations
2 Differentials
3 Integration
4 Data visualisation and fitting

IX. Solutions to exercises

X. Bibliography

XI. Index

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