God Found this Strong Man & Made Him an Awesome Psychiatric Nurse: Journal for Thoughts and Musings

Rabota Funktsionalizirovannye 2-etinil-4,5,6,7-tetragidroindoly: sintez i reaktsii atsetilenovykh zamestiteley posvyashchena razvitiyu reaktsii kross-sochetaniya bromatsetilenov s pirrol'nymi sistemami na aktivnykh poverkhnostyakh, a takzhe ispol'zovaniyu poluchennykh atsetilenovykh proizvodnykh v sinteze funktsionalizirovannykh 4,5,6,7-tetragidroindolov. Vozmozhnosti funktsionalizatsii pokazany na primere reaktsiy prisoedineniya k troynoy svyazi 2-etinil-4,5,6,7-tetragidroindolov aminov, aminokislot, bifunktsional'nykh nukleofilov i azid-aniona s vykhodom na ansambli tetragidroindolov s drugimi azolami. Izucheny peregruppirovki [2+2]-tsikloadduktov dikhlorditsianobenzokhinona i etinil-4,5,6,7-tetragidroindolov, otkryvayushchie put' k sintezu politsiklicheskikh ansambley, ob"edinyayushchikh pirrol'nye, tsiklobutenovye, tsiklopentenonovye i digidrofuranonovye struktury. Razrabotan metod polucheniya vtorichnykh propargilovykh spirtov s aromaticheskimi zamestitelyami iz al'degidov i atsetilena v sisteme KON/N2O/DMSO. Vtorichnye propargilovye spirty legko okisleny kislorodom v prisutstvii kataliticheskoy sistemy TEMPO/Fe(NO3)3•9H2O/NaCl, preimushchestva etogo metoda v atom-ekonomnosti i ekologichnosti po sravneniyu so stekhiometricheskimi variantami.