Electroanalytical Methods

Introduction
1. CONDUCTOMETRY
Electrolytic Conductance
Ohm's Law
Specific Conductance
Equivalent Conductance
Molar Conductance
Determination of Electrolytic Conductance
Types of Conductivity Cells
Conductivity Measurements
Immersed-Electrode Measurements
Electrodeless Measurements
Applications of Conductivity Measurements
Determination of Ionic Product of Water (KW)
Determination of Solubility of Sparingly Soluble Salts
Conductometric Titrations
Determination of Purity of Water
Concentration Determination
Ion Chromatography
Problems
References
2. POTENTIOMETRY
Principle
Instrumentation
Reference Electrodes
Indicator Electrodes
Analytical Information
Advantages
Applications
Potentiometric Titrations
Other Applications
Problems
References
3. VOLTAMMETRY
Polarography
Dc Polarography (Conventional Polarography)
Principle
Faradaic and Non-Faradaic Processes
Faradaic Current
Non-Faradaic Current
Polarographic Wave
Charging Current
Mass Transport
Limiting Currents
Polarographic Maxima
Instrumentation
Potentiostat
Electrochemical Cell
Two-electrode Polarograph
Three-electrode Polarograph
Inert Atmosphere
Quantitative Techniques
Wave Height-Concentration Plots
Internal Standard (Pilot Ion) Method
Method of Standard Addition
Pulse Polarography
Basic Principle
Normal Pulse Polarography
Differential Pulse Polarography
Pulse Voltammetry at Stationary Electrode
Applications
Fundamental Harmonic AC Polarography
Faradaic Electrode Processes
Chronopotentiometry
Linear Sweep Voltammetry and Related Techniques
Theory for Faradaic Processes
Coupled Chemical Reactions
Stripping Voltammetry
Anodic Stripping Voltammetry
Electrodes
Theory and Techniques
Cathodic Stripping Voltammetry
Adsorptive Stripping Voltammetry
Problems
References
4. AMPEROMETRY
Principle
Instrumentation
Amperometric Detection and Biosensors
Amperometric Titrations
Titrations with DME
Titrations with Rotating Pt Electrode
Biamperometric Titrations
Advantages of Amperometric Titrations
Applications
Problems
References
5. COULOMETRY
Controlled Potential Methods
Coulometric Measurements
Controlled Current Methods
Coulometric Measurements
Applications